OCCURRENCE AND MINERALOGICAL CHARACTERIZATION OF SPECULARITE IN DAMJAN ORE DEPOSIT, NORTH MACEDONIA
DOI:
https://doi.org/10.46763/GEOL25392103shiKeywords:
specularite; calcite; quartz; DamjanAbstract
In this paper are presented occurrence and mineralogical characterization of specularite from Damjan ore deposit. The straightforward identification of the studied mineral sample was enabled by SEM-EDS, XRF and XRPD methods. With these methods it can be seen that the phases present are calcite, specularite and quartz. Specularite crystals occur in the surface parts of the deposit. Specularite has a metallic gray to silvery appearance with a glittering luster and reddish streak. It shows a very smooth surface with reflection. The metallic luster is a result of the specific crystal formation of hematite. Manganese and aluminium substitute for Fe³⁺ in the specularite structure. Small amounts of Fe²⁺ and Mn2+ substitute for Ca²⁺ in the crystal lattice on calcite. The well-developed morphology of specularite suggests that it crystallized first. The finer-grained calcite likely formed later, filling the interstitial spaces between the earlier-formed specularite.
Downloads
References
[1] Boev, B., Jovanovski, G., Makreski, P. (2013): Minerals from Macedonia. XX. Geological setting, lithologies, and identification of the minerals from Ržanovo Fe–Ni deposit. Geologica Macedonica, 27 (1), 13–24.
[2] Chukanov, N. V. (2014): Infrared Spectra of Mineral Species: Extended Library. Part of the book se-riesSpringer Geochemistry / Mineralogy. Springer Science & Business Media.
[3] Chun, T.; Zhu, D. (2016): Oxidizing Roasting Performances of Coke Fines Bearing Brazilian Specularite Pel-lets. High Temp. Mater. Processes, 35, 615–620.
[4] Dolenec, M., (1959): Program investicione izgradnje rudnika magnetita Damjan – geološki deo. Stručen fond Skopske zelezare, Skopje (Damjan magnetite mine investment construction program – geological part. Professional Fund of Mines and Ironworks – Skopje).
[5] Guo, H., Shen, F., Jiang, X., Xiang, D., Zheng, H. (2020): Influence of iron ore concentrate on the characteristics of sintering and reduction of sinter, Journal of Mining and Metallurgay, Section B: Metallurgy, 56 (3), 337–351.
[6] Ivanov, T. (1965): Metalogenija južnog dela Vardarske zone. Doktorska disertacija, Beograd (Metallogeny of the southern part of the Vardar zone. Doctoral dissertation, Belgrade).
[7] Ivanov, T. (1966): Izveštaj za geološkata karta na rudniot reon Damjan-Bučim 1:10000. Stručen fond, na Geološki zavod Skopje.
[8] Ivanov, T., Veličković, S. (1976): Geologija rudnog reona Damjan–Bučim. VIII Kongres geologa. Jugoslavi-ja, Bled, Ljubljana (Geology of the Damjan-Buchim ore region. VIII Congress of Geologists. Yugoslavia, Bled, Ljubljana).
[9] Ivanov, T. (1982): Metalogenetska studija na rudniot reon Bučim Damjan Borov Dol. Stručen fond na Bučim (Metallogenetic study of the Bučim Damjan Borov Dol mining area. Professional fund in Bučim).
[10] Janković, S. (1967): Metalogenetske Epohe i Rudonosna Podračja Jugolslavije. Rudarski Institut, Beograd.
[11] Jankovic, S. (1972): Basic setting of metallogenetic analysis and creation of areas and regions. Аbstract of the first meeting on metallogenetic analyzes and metallogenetic maps of Yugoslavia. JK ILMS, Belgrade
[12] Kumar, S., Jaiswal, A,, Sah, R. (2022): Improving the sinter productivity with increased specular iron ore in sinter blend, J. Min. Metall. Sect. B – Metall. 58 (2) (2022) 261 – 273.
[13] Madejová, J., Gates, W. P., Petit, S. (2017): IR spectra of clay minerals. In: Infrared and Raman Spectros-copies of Clay Minerals, p. 107–149. Elsevier.
[14] Makreski, P., Jovanovski, G., Kaitner, B., Stafilov, T., Boev, B., Cibrev, D. (2004): Minerals from Macedonia. X. Sepration and identification of some oxide minerals by FT IR spectroscopy, AAS, AES ICP and powder XRD. Neues Jahrbuch für Mineralogie – Abhandlungen, 180, 215–243.
[15] Naito, M., Takeda, K., Matsu, Y. (2014): Ironmaking technology for the last 100 years: from adopted tehnologies to a position of leadership in advanced and next generation technology. Tetsu-To-Hagane/Journal of the Iron and Steel Institute of Japan, 100 (1), 2–30.
[16] Rendon, J. L., Serna, C. J. (1981): IR spectra of powder hematite: effects of particle size and shape. Clay Minerals, 16 (4), 375 381.
[17] Restrepo Baena, O. J., Forero Pinilla, Á., Dıaz Bello, S. (2009): Characterization and concentration of specularite as natural pigment for to manufacture anticorrosives paints, Revista Mexicana de Física S, 55 (1) 123–126.
https://www.redalyc.org/articulo.oa?id=57030347029
[18] Ruan, H. D., Frost, R. L., Kloprogge, J. T., Duong, L. (2002): Infrared spectroscopy of goethite dehydrox-ylation: III. FT-IR microscopy of in situ study of the thermal transformation of goethite to hematite. Spectro-chimica Acta. Part A: Molecular and Biomolecular Spectroscopy, 58 (5), 967–981.
[19] Serafimovski, T. (1982): Metalogenetske karakteristike Fe ležišta Damjan. Magistarski rad, Beograd.
[20] Serafimovski, T. (1986): Geološke karakteristike skarnovskog Fe ležista Damjan, XI Kongres geologa Jugoslavije, Tara.
[21]Serafimovski, T. (1993): Structural-Metallogenic Features of the Lece-Chakidiki Zone: Types of Mineral Deposits and Distribution. University Sv. Kiril i Metodij Skopje, Faculty of mining and geology, Special is-sue No 2.
[22] Shontevska, V., Jovanovski, G., Makreski, P., Raškovska, A., Šoptrajanov, B. (2008): Minerals from Mace-donia. XXI. Vibrational spectroscopy as identificational tool for some phyllosilicate minerals. Acta Chimica Slovenica, 55 (4), 757–766.
[23] So, R. T., Blair, N. E., Masterson, A. L. (2020): Carbonate mineral identification and quantification in sedi-ment matrices using diffuse reflectance infrared Fourier transform spectroscopy. Environmental Chemistry Letters, 18, 1725–1730.
[24] Wu, Sl., Que, Zg., Li, Kl. (2018): Strengthening granulation behavior of specularite concentrates based on matching of characteristics of iron ores in sintering process, Journal of Iron and Steel Research Internation-al, 25, 1017–1025. https://doi.org/10.1007/s42243-018-0153-9
[25] Zhu, X., Han, Y., Cao, Y.,Sun, Y., Li, Y. (2022): Magnetization roasting of specularite ore: Phase transformation, magnetism and kineticss. Mineral Processing and Extractive Metallurgy Review, 44 (5), 346–351. https://doi.org/10.1080/08827508.2022.2068010
[26] Zarić, P. (1977): Tipomorfne metalogenetske karakteristike mag¬netita Jugoslavije. PHD thesis, Beograd.