Spatial distribution of heavy metals in soils in the Republic of Macedonia

  • Marjan Mihajlov
  • Lambe Barandovski
  • Robert Šajn
  • Trajče Stafilov

Abstract

The distribution of various elements in soils in the Republic of Macedonia was analyzed in termsof air pollution with heavy metals carried out for more than 10 years within the European moss biomonitoring programmeof air pollution in Europe. In 2010 in parallel to moss sampling, on the same locations, soil samples were alsocollected using a network of 72 locations all over the country. In total of 144 samples (top and bottom soil) werecollected and 18 elements (Al, Ba, Ca, Cr, Cu, Fe, Ga, K, Li, Mg, Mn, Na, Ni, P, Pb, Sr, V and Zn) were analyzed usinginductively coupled plasma – atomic emission spectrometry (ICP-AES). Both, top and bottom soil samples wereanalyzed to identify possible anthropogenic influences and to assess whether the metal content is associated with anthropogenicsources or it is a result of lithology. The obtained data were statistically processed and distribution mapsfor all analyzed elements were prepared. The results are compared with international standards for soil and with thelocations of the industry. The analysis generally indicates a connection with the lithological appearances, but alsoshows a possible association with certain industrial activities.

Downloads

Download data is not yet available.

References

Angelovska, S., Stafilov, T., Šajn, R., Bačeva, K., Balabanova, B.: Moss biomonitoring of air pollution with heavy metals in the vicinity of Pb-Zn mine “Toranica” near the town of Kriva Palanka. Modern Chemistry & Applications, 2 (1), 123, 1–6 (2014).

Arsovski, M.: Importance of the stratigraphic distinguishing the Paleozoic schists in Western Macedonia for the geological investigation of iron deposits. Book of Papers of Geological Survey of Macedonia, 9, 2–22 (1962) (in Serbian).

Arsovski, M., Dumurdžanov, N.: Recent findings of the structure of Pelagonian Horst Anticlinorum and its relation with the Rhodopean and Serbo-Macedonian massif. Geologica Macedonica, 1, 3–25 (1984).

Arsovski, M., Dumurdžanov, N.: Alpine tectonic evolution of the Vardar zone and its place in the Balkan region. Geologica Macedonica, 9, 15–22 (1995).

Artiola, J. F., Pepper, I., Brussean, L.: Environmental Monitoring and Characterization. Elsevier Academic Press, San Diego, 2004.

Bačeva, K., Stafilov, T., Šajn, R., Tănăselia, C., Ilić Popov, S.: Distribution of chemical elements in attic dust in the vicinity of ferronickel smelter plant. Fresenius Environmental Buletin, 20 ( 9), 2306–2314 (2011).

Bačeva, K., Stafilov, T., Šajn, R., Tănăselia, C.: Moss biomonitoring of air pollution with heavy metals in the vicinity of a ferronickel smelter plant. Journal of Environmental Science and Health, Part A, 47 (4), 645– 656 (2012).

Balabanova, B., Stafilov, T., Bačeva, K., Šajn, R.: Biomonitoring of atmospheric pollution with heavy metals in the copper mine vicinity located near Radoviš, Republic of Macedonia. Journal of Environmental Science and Health, Part A, 45, 1504–1518 (2010).

Balabanova, B., Stafilov, T., Šajn, R., Bačeva, K.: Distribution of chemical elements in attic dust as reflection of lithology and anthropogenic influence in the vicinity of copper mine and flotation. Archive of Environmental Contamination and Toxicology, 61, 173–184 (2011).

Balabanova, B., Stafilov, T., Šajn, R., Bačeva, K.: Spatial distribution and characterization of some toxic metals and lithogenic elements in topsoil and subsoil from copper mine environs. International Journal of Environmental Protection, 3, 1–9 (2013).

Balabanova, B., Stafilov, T., Šajn, R., Bačeva, K.: Comparison of response of moss, lichens and attic dust to geology and atmospheric pollution from a copper mine. International Journal of Environmental Science and Technolology, 11, 517–528 (2014).

Balabanova, B., Stafilov, T., Šajn, R.: Variability assessment for multivariate analysis of elemental distributions due to anthropogenic and geogenic impact in lead-zinc mine and flotation environ (moss sampling media). Geologica Macedonica, 28 2), 35–41 (2014).

Balabanova, B., Stafilov, T., Šajn, R., Bačeva, K.: Quantitative assessment of metal elements using moss species as biomonitors in downwind area of one lead-zinc mine. Journal of Environmental Sciences, (2016), in press; DOI: 10.1016/S1001-0742(13)60561-6.

Barandovski, L., Frontasyeva, M. V., Stafilov, T., Šajn, R., Pavlov, S., Enimiteva. V.: Trends of atmospheric deposition of trace elements in Macedonia studied by the moss biomonitoring technique. Journal of Environmental Sciences and Health, Part A, 47, 2000–2015 (2012).

Barandovski, L., Stafilov, T., Šajn, R., Frontasyeva, M. V., Bačeva, K.: Air pollution study in Macedonia by using moss biomonitoring technique, ICP-AES and AAS. Macedonian Journal of Chemistry and Chemical Engineering, 32 (1), 89–107 (2013).

Barandovski, L., Frontasyeva, M. V., Stafilov, T., Šajn, R., Ostrovnaya, T.: Atmospheric deposition of trace elements in Macedonia studied by the moss biomonitoring technique. Environmental Science and Pollution Research, 22 (20), 16077–16097 (2015).

Davis, J. C.: Statistic and Data Analysis in Geology. Willey in Sons, New York, 1986.

Dumurdžanov, N.: Devonian magmatic rocks in Western- Macedonian Zone (SR Macedonia – Yugoslavia). Geologica Macedonica, 3, 57–78 (1987).

Garson, D.: Factor Analysis. North Carolina State University, Raleigh, 2000.

Jovanovski, G., Boev, B., Makreski P.: Minerals from the Republic of Macedonia with and Introduction to Mineralogy. Macedonian Academy of Science and Arts, Skopje, 2012.

Kabata-Pendias, A., Pendias, H.: Trace Elements in Soil and Plants. Third Edition, CRC Press, Boca Raton, 2001.

Kabata-Pendias, A., Mukherjee, A. B.: Trace elements from soil to human. Springer-Verlag, Berlin, Heidelberg, 2007.

Šajn, R.: Using attic dust and soil for the separation of anthropogenic and geogenic elemental distributions in an old metallurgic area (Celje, Slovenia). Geochemistry: Exploration, Environment, Analysis, 5, 59–67 (2005).

Šajn, R.: Factor analysis of soil and attic-dust to separate mining and metallurgy influence, Meža Valley, Slovenia. Mathematical Geology, 38, 735–747 (2006).

Sherameti, I., Varma, A.: Soil Biology: Soil Heavy Metals, Springer-Verlag, Berlin-Heidelberg, 2010.

Salminen, R., Batista, M. J., Bidovec, M., Demetriades, A., De Vivo, B., De Vos, W., Duris, M., Gilucis, A., Gregorauskiene, V., Halamic, J., Heitzmann, P., Jordan, G., Klaver, G., Klein, P., Lis, J., Locutura, J., Marsina, K., Mazreku, A., O’Connor, P. J., Olsson, S. Å. , Rottesen, T., Petersell, V., Plant, J. A., Reeder, S., Salpeteur, I., Sandström, H., Siewers, U., Steenfelt, A., Tarvainen, T.: Geochemical Atlas of Europe, Part 1, Background Information, Methodology and Maps. Geological Survey of Finland, Espoo, 2005.

Stafilov, T., Šajn, R., Pančevski, Z., Boev, B., Frontasyeva, M. V., Strelkova, L. P.: Geochemical Atlas of Veles and the Environs. Faculty of Natural Sciences and Mathematics, Skopje, 2008.

Stafilov, T., Šajn, R., Boev, B., Cvetkovič, J., Mukaetov, D., Andreevski, M.: Geochemical Atlas of Kavadarci and the Environs. Faculty of Natural Sciences and Mathematics, Skopje, 2010a.

Stafilov, T., Šajn, R., Pančevski, Z., Boev, B., Frontasyeva, M. V. and Strelkova, L. P.: Heavy metal contamination of surface soils around a lead and zinc smelter in the Republic of Macedonia. Journal of Hazardous Materials, 175, 896–914 (2010b).

Stafilov, T., Šajn, R., Boev, B., Cvetkovič, J., Mukaetov, D., Andreevski, M., Lepitkova, S.: Distribution of some elements

in surface soil over the Kavadarci region, Republic of Macedonia. Environmental Earth Sciences, 61, 1515– 1530 (2010c).

Stafilov, T., Balabanova, B., Šajn, R., Bačeva, K., Boev, B.: Geochemical Atlas of Radoviš and the Environs and the Distribution of Heavy Metals in the Air. Faculty of Natural Sciences and Mathematics, Skopje, 2010d.

Stafilov, T., Balabanova, B., Šajn, R.: Geochemical Atlas of the Region of the Bregalnica River Basin. Faculty of Natural Sciences and Mathematics, Skopje, 2014.

Tompson, N., Serafimovski, T., Kochneva, N. T.: Cenozoic metallogeny of eastern Macedonia. Geology of Ore Deposits, 40, 175–183 (1998).

Zhang, C., Selinus, O., Schedin, J.: Statistical analyses for heavy metal contents in till and root samples in an area of southern Sweden. Sciience of the Total Environment, 212, 217–232 (1998).

Published
2016-06-08
How to Cite
Mihajlov, M., Barandovski, L., Šajn, R., & Stafilov, T. (2016). Spatial distribution of heavy metals in soils in the Republic of Macedonia. Geologica Macedonica, 30(1), pp. 41-. Retrieved from https://js.ugd.edu.mk/index.php/GEOLMAC/article/view/1430