Earthy–Cryptocrystalline vivianite from the trepel deposits near the Suvodol village, Bitola, Macedonia
Abstract
Within the frame of the trepel deposits (Fig. 1) near Suvodol village, Bitola city it was discovered(Lj. Petreski) an earthy-cryptocrystalline vivianite occurrence. The examined vivianite sample was confirmed byX-ray powder diffraction, chemical, SEM, DTA/TG, infra-red analyses. The treated vivianite sample actually representsa typical earthy-cryptocrystalline variety (Fig. 2) with a peculiar progressive oxidation state of Fe2+ to Fe3+(FeO/Fe2O3 contents nearly 1:1). X-ray powder diffraction, DTA/TG-data are in quite good concordance with literaturedata.Downloads
References
Marković-Marijanović J., 1956: Vivianit vo kvartarnite sedimenti na Bitolskiot basen. Trudovi na Geoloshkiot Zavod na N.R. Makedonija, Fasc. 5, Skopje.
Stojanov R., 1958: Prethodni rezultati od geološkite i petrografskite istražuvanja na Selečka planina. Trudovi na Geološkiot zavod na N. R. Makedonija, Fasc. 6, Skopje.
Sameshima, Henderson G. S., Black P. M., Rodgers K. A., 1985: X-ray diffraction studies of vivianite, meta-vivianite and baricite. Min. Magazine, Vol. 49, p-p 81–85, March.
Pratt A. R., 1997: Vivianite auto-oxidation. Phys. Chem. Minerals; Springer–Verlag, 25, 24–27.
R. L. Frost, W. Martens, P. A. Williams and J. T. Kloprogge, 2002: Raman and infrared spectroscopic study of the vivianite – group phosphates vivianite, baricite and bobierrite.
Min. Magazine, 66, 6, 1063–1073, December.
Ray L. Frost; Matt. Weier, Wayde Martens, J. Theo Kloprogge, Zhe Ding, 2003: Dehydration of synthetic and natural vivianite. Thermochimica Acta, 401, 121–130.