Mineralogical characteristics of kyanite from Prilepec, Republic of Macedonia
Abstract
This paper gives mineralogical characteristics of kyanite from village of Prilepec, R.Macedonia. Several samples were collected for research. The kyanite was identified by Scanning electronmicroscopy (SEM), coupled with an energy dispersive X-ray spectrometer (EDS), X-ray diffraction(XRD) and Infra red spectroscopy (IR). The use of these three methods showed that they are very usefulmethods for rapid mineral analysis contributing important analytical information.The results of the X-raypowder pattern, SEM analysis and Infra red spectroscopy enable straightforward identification of thestudied mineral sample as kyanite. Kyanite is located east of village of Prilepec in micashist rocks whichhave lepidoblastic structure and schistose texture. It occurs in blue thin-bladed triclinic crystals and crystallineaggregates. Cleavage is perfect on {100}, good on {010}. Fracture is splintery. Kyanite is transparentto translucent. Lustre is vitreous or sub-vitreous. Hardness lengthwise 4–5, crosswize 6–7. Density3.53–3.67 g/cm3 .The colour is blue. Origin on blue colouris due to the charge-transfer process Fe2+ →Fe3+, Fe2+ Ti4+ or Cr3+. In our samples concentration of Fe is 0.05–0.18 wt%, Ti concentration is 0.03–0.11 wt%, while Cr concentration is 0.02–0.13 wt%.Downloads
References
Albee, A. L., Chodos, A. A.: Minor element content of coexistent Al2SiO5 polymorphs. Amer. J. Sci., 267, 310– 316 (1969).
Бариќ, Љ.: Дистен андалузит и силиманит на подрачјето на Југославија, Трудови на Геолошкиот завод, Скопје, книга 5 (1956).
Burnham, C. W.: Refinement of the crystal structure of kyanite. Z. Kristallogr., II, 8, 337–360 (1963).
Cnooos: Minor element content of coexisting Al2SiO5 polymorphs. Amer. J. Sci. 267, 310–316 (1969).
Comodi, P., Zanazzi, P. F., Poli, S. and Schmidt, M. W.: High pressure behavior of kyanite: decomposition of kyanite into stishovite and corundum. American Mineralogist, 82, 460–466 (1997).
Deer, W. A., Howie, R. A. and Zussman, J.: Rock Forming Minerals, 1, 137–43 (1962).
Faye, G. H., Manning, P. G. & Nickel, E. H.: The polarized optical absorption spectra of tourmaline, cordierite, chloritoid and vivianite: Ferrous-ferric electronic interaction as a source of pleochroism. Amer. Mineral, 53, 1174–1201 (1968).
Fаye, G. H.: The optical absorption spectra of iron in sixcoordinate sites inchlorite, biotite, phlogopite and vivianite. Some aspects of pleochroism in the sheet silicates. Can. Mineral. 9, 403–425 (1968a).
Faye, G. H. and Nickel, E. H.: On the origin of colour and pleochroism of kyanite. Can. Mineral. 10, 35–46 (1969).
Griffiths, P. R., De Haseth, J. A.: Furier Transform Infrared Spectrometry (2nd Edition), John Wiley & Sons, pp. 349–355, 2007.
Herz, N., Dutra, C. V.: Am. Mineral. 49, 1290–305 (1964).
Hurlbut, C. S. JR., Klein, C.: Dana’s Manual of Mineralogy. 19th ed., John Willey and Sons, New York, 532 p., 1977.
Kerrick, D. M.: The Al2SiO5 polymorphs. In: Mineralogical Society of America Reviews in Mineralogy, 22, 1–406 (1990).
Langer, K. and Sharma, K. K.: Al2SiO5, Al2GeO5 and Cr2GeO5 kyanites: X-ray powder data and infrared absorption spectra, J. Appl. Cryst., 8, pp. 329–332 (1975).
Manninig, P. G. & Nickel, E. H.: A spectral study of the origin of colour and pleochroism of a titanaugite from Kaiserstuhl and of a riebeckite from St. Peter's Dome. Colorado. Can. M'ineral (1969).
Маринковиħ С.: Извештај о студии концентрације дистена из микашиста код Прилепца. Стручен фонд на Геолошкиот завод на НРМ, Скопје, 1955.
Naray-Szabo, St.: The structure of staurolite. Z. Kristallogr., 7, 103–116 (1929).