CHEMICAL COMPOSITION OF SOME AUTOCHTHONOUS FRUIT SPECIES FROM MACEDONIA
Abstract
The scope of this paper is determination of the content of soluble dry matters, total sugar, total acids, invert sugar and citric, malic, tartaric and lactic acid in some autochthonous fruit species: pomegranate (Zumnarija, Bejnarija, Valandovska kisela, Valandovska kiselo-slatka, Hidjas, Kisela, Lifanka, Ropkavec), apple (Ubavo cvetka, Shareno blago, Prespanka, Tetovka, Karapasha, Kozharka, Bela Tetovka) and cherry (Ohridska brza, Ohridska rana, Ohridska crna, Dolga shishka, Dalbazlija, Ohridska bela). Comparative studies were performed in relation to the standard varieties (Karamustafa-pomegranate, Idared-apple and Bigaro burlat-cherry).
Pomegranate fruits have the highest content of soluble dry matters (15.6%), total sugars (149.24 g/L) and total acids (20.11 g/L). The highest content of invert sugar was observed in pomegranate (113.94 g/L which means 76.3% of total sugar). In apple and cherry fruits, malic acid dominates (above 5 g/L), while in pomegranate fruits, citric and malic acids are almost equally represented. Tartaric acid is present only in apple fruits (0.383 g/L). Lactic acid was not found in all fruit species.
A strong positive correlation was found between soluble dry matter and total sugar (R2 is about 60%). A moderate positive correlation exists between the contents of total and invert sugar (R2 is about 20%), between total acids and invert sugar (R2 is about 22%) and between the content of malic and citric acid (R2 is about 30%). A high negative correlation was found between the content of total acid and malic acid (R2 is about 37%) and between malic acid and invert sugar (R2 shows 77%).
References
2. Gűndoğdu, M. & Bilge U. (2012). Determination of organics, phenolics, sugars and vitamin C contents of some cherry cultivars (Prunus avium). International J. Agric. & Biol. 14: 595-599. http://www. fspublishers.org
3. Hayaloglu, A. & Demir, N. (2015). Physicochemical characteristics, antioxidant activity, organic acid and sugar contents of 12 sweet cherry (Prunus avium L.) cultivars grown in Turkey. Journal of Food Science. https://doi.org/10.1111/1750-3841.12781
4. Iniċ, S., Ljepoviċ, M., Domijan, A., Steiner, A., Srdareviċ S., Jablan J. & Markov K. (2020). HPLC Analysis of Citric and Tartaric Acids in Fruit Nectars and Juices. Croat. Chem. Acta, 93(1), 57-62. https://doi.org/10.5562/cca3662
5. ISO 750:1998. Fruit and vegetable products-Determination of titratable acidity.
6. Li, J., Zhang, C., Liu, H., Liu J. & Jiao A. (2020). Profiles of sugar and organic acid of fruit juices: A comparative study and implication for authentication. Hindawi, https://doi.org/10.1155/2020/7236534
7. Ma, B., Yuan, Y., Gao, M., Li, C., Ogutu, C., Li M. & Ma F. (2018). Determination of predominant organic acid components in Malus species: Correlation with Apple Domestication. Metabolites 8(4):74. https://doi.org/10.3390/metabo8040074.
8. Markovski, A., Gjamovski V. & Popovska M. (2017). Investigation of aril characteristics of some autochtonous pomegranate (Punica granatum L.) varieties in Macedonia. Agroknowledge, 18, 2, 109-119. https://doi.10. 7251/AGREN1702109М
9. Mayuoni-Kirshinbaum, L. & Porat R. (2014). The flavor of pomegranate fruit: a review. J.Sci Food Agric, 94 (1), 21-7. https://doi.org/10.1002/jsfa.6311
10. Naqvi, R. (2017). Acute kidney injury from different poisonous substances. World J. Nephrol, 6, 162-167. https://doi.org/ 10.5527/wjn.v6.13.162
11. Nishyama, I., Fukuda, T., Shimonashi, A. & Oota T. (2008). Sugar and organic acid composition in the fruit juice of different Actinidia varieties. Food Science and Technology, 14(1), 67-73. https://doi.10.3136/fstr.14.67
12. Poyrazoğlu, E., Gökmen, V. & Artik N. (2002). Organic acids and phenolic compounds on pomegranates (Punica granatum L.) grown in Turkey. Journal of Food Composition and Analysis, 15, 5, 567-575. https://doi.org/10.1006/jfca.2002.1071
13. Ren, Y.F., Amin, A. & Malmstrom, H. (2009). Effects of tooth whitening and orange juice on surface properties of dental enamel. J. Dent., 37, 424-431. https://doi.org/ 10.1016/j.dent. 2009.01.011.
14. Rusyniak, D.E., Durant, P.J., Mowry, J.B., Johnson, J.A., Sanftleben, J.A. & Smith, J.M. (2013). Life-threatening hyperkalemia from cream of tartar ingestion. J. Med. Toxical, 9(1), 79-81. https://doi:10.1007/s 13181-012-0255
15. Selamovska, A & Miskoska-Milevska, E. (2021). Fruits as food and medicine. Skopje, Republic of Macedonia.
16. Sokol-Letowska, A., Kucharska, A.Z., Hodun, G. & Golba, M. (2020). Chemical composition of 21 cultivars of sour cherry (Prunus cerasus) fruit cultivated in Poland. Molecules, 25(19), 4587. https://doi.org/10.3390/molecules 25194587
17. Usenik, V., Fabčiċ, J. & Štampar, F. (2008). Sugars, organic acids, phenolic composition and antioxidant activity of sweet cherry (Prunus avium L.). Food Chemistry, 107, 1, 185-192. https://doi.org/10.1016/j.foodchem.2007.08.004
18. Wu, J., Fan, J., Li, Q., Jia, L., Xu, L., Wu, X., Wang, Z, Li, H., Qi, K., Qiao, X., Zhang, S. & Yin, H. (2022). Variation of organic acids in mature fruits of 193 pear (Pyrus spp.) cultivars. Journal of Food Composition and Analysis, 109, 104483. https://doi.org/10.1016/j.jfca.2022.104483
19. Zhang, J., Nie, J., Li, J., Zhang, H., Li, Y., Farooq, S., Bacha, S.A. & Wang J. (2020). Evaluation of sugar and organic acid composition and their levels in highbush blueberries from two regions of China. Journal of integrative Agriculture, vol. 19, 9:2352-2361. https://doi:10.1016/S2095-3119(20)63236-1